The angle of incidence of a ray in a denser medium for which the angle of refraction in rare medium is 90°, is called Critical angle for those pair of media.
When a ray of light travels from denser to rarer medium at the angle of incidence greater than critical angle for the pair of media, the ray gets reflected back to the denser medium without any loss of energy. This phenomenon is called total INTERNAL reflection.
Red rose appears red in white light because it reflects red colour and absorbs all the other colours of white light, but appears black in green colour because the only colour given to the flower is absorbed and nothing is reflected.